Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes.
نویسندگان
چکیده
In weakly coordinating solvents FeII meso-(N-methylimidazol-2-yl)porphine Fe exists as a stable dimer (Kd=50+/-30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.
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ورودعنوان ژورنال:
- Chemical communications
دوره 8 شماره
صفحات -
تاریخ انتشار 2008